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31.
浙江省入境旅游发展势头强劲,但省内各地市间入境旅游发展却参差不齐,非均衡性空间特征显著。通过分析浙江省11个地市1999—2008年共10年的入境旅游外汇收入指标,引入标准差、相对发展率和波士顿矩阵等分析方法,归纳浙江省入境旅游发展空间非均衡基本特征,同时,对影响非均衡产生的经济社会条件、区位条件、资源环境等因子的变化趋势进行深入探究,提出浙江省入境旅游可以由非均衡发展逐步向均衡化方向发展的观点。最后,从浙江省资源整合、区域联动角度,提出了浙江省入境旅游均衡化发展的对策思路。  相似文献   
32.
为了优选用于河岸、库岸等间歇性淹水地区植被恢复的适生树种,研究了30d完全淹水解除后互叶白干层(Melaleuca alternifolia)幼苗气体交换特性、叶绿素荧光特性和质膜透性的恢复情况.在全淹30d及退水后70d的恢复生长过程中,互叶白干层成活率为100%.经过30d的全淹处理,互叶白干层的叶绿素含量、净光合...  相似文献   
33.
The remediation strategy for an industrial site located in a coastal area involves a pump and treat system and a horizontal flow barrier (HFB) penetrating the main aquifer. To validate the groundwater flow conceptual model and to verify the efficiency of the remediation systems, we carried out piezometric measurements, slug tests, pumping tests, flowmeter tests and multilevel sampling. Flowmeter tests are used to infer vertical groundwater flow directions, and base exchange index is used to infer horizontal flow directions at a metric scale. The selected wells are located both upstream and downstream of the HFB. The installation of the HFB produced constraints to the groundwater flow. A stagnant zone of contaminated freshwater floating over the salt wedge in the upper portion of the aquifer is detected downstream of the HFB. This study confirms that the adopted remediation system is efficiently working in the area upstream of the HFB and even downstream in the bottom part of the aquifer. At the same time, it has also confirmed that hot spots are still present in stagnant zones located downstream of the HFB in the upper part of the aquifer, requiring a different approach to accomplish remediation targets. The integrated approach for flow quantification used in this study allows to discriminate the direction and the magnitude of groundwater fluxes near an HFB in a coastal aquifer. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
34.
The coupling between biogenic reworking activity and reactive organic matter patterns within deposits is poorly understood and often ignored. In this study, we examined how common experimental treatments of sediment affect the burrowing behavior of the polychaete Nephtys incisa and how these effects may interact with reactive organic matter distributions to alter diagenetic transport – reaction balances. Sediment and animals were recovered from a subtidal site in central Long Island Sound, USA. The upper 15 cm of the sediment was sectioned into sub-intervals, and each interval separately sieved and homogenized. Three initial distributions of sediment and organic substrate reactivity were setup in a series of microcosms: (1) a reconstituted natural pattern with surface-derived sediment overlying sediment obtained from progressively deeper material to a depth of 15 cm (Natural); (2) a 15 cm thick sediment layer composed only of surface-derived sediment (Rich); and (3) a 15 cm thick layer composed of uniformally mixed sediment from the original 15 cm sediment profile (Averaged). The two last treatments are comparable to that used in microcosms in many previous studies of bioturbation and interspecific functional interaction experiments. Sediment grain size distributions were 97.5% silt-clay and showed no depth dependent patterns. Sediment porosity gradients were slightly altered by the treatments. Nepthys were reintroduced and aquariums were X-rayed regularly over 5 months to visualize and quantify spatial and temporal dynamics of burrows. The burrowing behaviour of adult populations having similar total biovolume, biomass, abundance, and individual sizes differed substantially as a function of treatment. Burrows in sediment with natural property gradients were much shallower and less dense than those in microcosms with altered gradients. The burrow volume/biovolume ratio was also lower in the substrate with natural organic reactivity gradients. Variation in food resources or in sediment mechanical properties associated with treatments, the latter in part coupled to remineralization processes such as exopolymer production, may explain the burrowing responses. In addition to demonstrating how species may respond to physical sedimentation events (substrate homogenization) and patterns of reactive organic matter redistribution, these experiments suggest that infaunal species interactions in microcosms, including the absolute and relative fluxes of remineralized solutes, may be subject to artifacts depending on exactly how sediments are introduced experimentally. Nonlocal transport and cylinder microenvironment transport – reaction models readily demonstrate how the multiple interactions between burrowing patterns and remineralization rate distributions can alter relative flux balances, decomposition pathways, and time to steady state.  相似文献   
35.
In our previous study, we developed the Stokes–Darcy (SD) model was developed for flow in a karst aquifer with a conduit bedded in matrix, and the Beavers–Joseph (BJ) condition was used to describe the matrix–conduit interface. We also studied the mathematical well‐posedness of a coupled continuum pipe flow (CCPF) model as well as convergence rates of its finite element approximation. In this study, to compare the SD model with the CCPF model, we used numerical analyses to validate finite element discretisation methods for the two models. Using computational experiments, simulation codes implementing the finite element discretisations are then verified. Further model validation studies are based on the results of laboratory experiments. Comparing the results of computer simulations and experiments, we concluded that the SD model with the Beavers–Joseph interface condition is a valid model for conduit–matrix systems. On the other hand, the CCPF model with the value of the exchange parameter chosen within the range suggested in the literature perhaps does not result in good agreement with experimental observations. We then examined the sensitivity of the CCPF model with respect to the exchange parameter, concluding that, as has previously been noted, the model is highly sensitive for small values of the exchange parameter. However, for larger values, the model becomes less sensitive and, more important, also produces results that are in better agreement with experimental observations. This suggests that the CCPF model may also produce accurate simulation results, if one chooses larger values of the exchange parameter than those suggested in the literature. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
36.
Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m‐2 d‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m‐2 d‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g‐1 d‐1) compared to alternating sites (<220 nmol g‐1 d‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
37.
We calculate the local energy and the energy density of the Reisner--Norstrõm--anti-de-Sitter black hole, study the first law of thermodynamics and show the Smarr formula for the Born--Infeld--anti-de-Sitter black hole. Applying the first law of thermodynamics to the black hole region, we analyse the three energy exchange processes between the black hole region and the outer and the inner regions.  相似文献   
38.
为了揭示河床沉积物非均质性对潜流交换的影响,构建了沙波地形作用下的地表水-地下水耦合模型,通过生成不同的渗透系数随机场,讨论了不同地表水动力过程和河床沉积物非均质性对潜流交换通量、交换空间及平均停留时间的影响规律。结果表明,所构建的地表水-地下水耦合模型能够准确刻画水沙界面附近流场,模型具有良好的适用性;均质或非均质河床沉积物情景下,水沙界面上的平均交换通量、停留时间与雷诺数之间均呈现幂函数关系,潜流交换深度则在地表水进入完全紊流之后趋于稳定。结果还表明,较强的河床沉积物非均质性能够有效增强水沙界面上潜流交换通量和空间交换频率,但会制约潜流交换空间并缩短水流在潜流带中的停留时间。  相似文献   
39.
天然水体中存在同化二氧化碳(CO2)的光合作用,也存在释放CO2的微生物呼吸过程。地球表层水体与大气之间的CO2交换构成全球碳循环的一个重要环节。水-气之间CO2交换的方向和通量主要受大气圈和水体表层CO2分压(pCO2)的制约。水体pCO2值可以通过对近水面气体成分变化过程的现场仪器检测或者根据测定的水体化学参数运用经验公式计算求得。迄今对陆地水体,尤其河流筑坝形成的"蓄水河流"(下称水库)水体CO2动态研究中,由于水域及其近表层大气成分的时空多变,一般采用水化学参数计算方法求得水体的pCO2值。全球约70.97%的水库表层水体pCO2高于大气pCO2。全球尺度上水库表层水体pCO2自热带向寒温带逐渐递减;单个水库水体的pCO2一般呈现"出库>入库>库中"、pCO2随深度而增加的变化规律。水库表层水体pCO2的时间变化一般表现为"冬季>夏季、消融期>冰冻期、黑夜>白天"。水库水体的pCO2是其水化学平衡的结果,受水温、水体pH、水生生物活动以及外来水体的混合等多种因素影响,变化较为复杂。为精确量化水库水-气界面CO2交换通量,水文学、湖沼学、生态学和地球化学等领域的学者有必要合作,共同努力进行水库流域尺度的实地观测,完善水体溶解无机碳计算模型,深入探讨水库水体碳动力学机制,为全球碳循环研究和气候变化预测提供可靠的基础数据。  相似文献   
40.
以0.004~0.80 mol.L-1的Na2SO4溶液为交换介质,测定了层状复合氢氧化物(LDH)[Mg4.7Al(OH)11.4]Cl0.96(OH)0.04.7.9H2O在超声条件下的离子交换容量和交换平衡常数。结果显示层间Cl-离子的最大交换容量为1.497 mmol.g-1,OH-离子的最大交换容量为0.026 8 mmol.g-1,交换平衡常数pK值为3.65;固相的XRD、IR及BET-N2表征显示交换反应后SO42-的Td对称性降低,LDH的晶胞参数c和通道高度h增大,结晶度下降,微晶的层间吸附活性降低,微孔吸附容量减小。  相似文献   
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